Partition function

The partition function sums the Boltzmann factors over all microstates of a system in thermal equilibrium at inverse temperature beta. It is the starting point for computing thermodynamic quantities such as free energy, energy and entropy.

Z(\beta) = \sum_i \exp(-\beta E_i)

What the symbols mean

canonical partition function, dimensionless, as a function of \beta
inverse temperature, \beta = 1/(k_B T), in units of 1/energy
energy of the i-th microstate, in joules
index running over all microstates of the system

About this formula

  • FieldPhysics
  • TopicStatistical mechanics
  • LevelUniversity
  • Also calledcanonical partition function, statistical sum over states, Boltzmann sum, partition function statistical mechanics, sum over states exp(-beta E)
  • SourceWikidata Q230963

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