Gibbs phase rule

Gives the number of independent intensive variables (degrees of freedom) that can be varied without changing the number of phases in a system at equilibrium. It is used to analyse how many conditions such as temperature or pressure can be set independently in a multicomponent, multiphase system.

F = C - P + 2

What the symbols mean

degrees of freedom (number of independent intensive variables)
number of components in the system
number of phases present at equilibrium

About this formula

  • FieldChemistry
  • TopicThermodynamics
  • LevelUniversity
  • Also calledphase rule, degrees of freedom equilibrium, number of degrees of freedom, Gibbs phase rule formula, phase equilibrium rule
  • SourceWikidata Q752412

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