Van der Waals equation

An equation of state for real gases that extends the ideal gas law by adding a term for attractive forces between molecules and a term for the finite volume they occupy. It is used to estimate the pressure, volume, or temperature of a real gas, especially near condensation or at high pressure.

\left(p + \frac{a}{V_\mathrm{m}^2}\right)\left(V_\mathrm{m} - b\right) = RT

What the symbols mean

pressure (Pa)
molar volume (m^3/mol)
thermodynamic temperature (K)
molar gas constant (J/(mol·K))
measure of attraction between gas molecules (Pa·m^6/mol^2)
volume excluded per mole by the molecules (m^3/mol)

About this formula

  • FieldPhysics
  • TopicThermodynamics
  • LevelUniversity
  • Also calledVan der Waals equation of state, van der Waals gas law, real gas equation, real gas law, non-ideal gas equation
  • SourceWikidata Q254329

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